Lecture 15 - Chemical Reactions I, Nomenclature III

Tuesday, March 5, 2024

1:30 PM

"In organic chemistry, there is no shortage of reactions, but rather a continual expansion as we understand more about the molecular fabric of our world. Each reaction is a unique dialogue between molecules, governed by their structure, reactivity, and the conditions under which they meet."
﷟HYPERLINK "https://www.nobelprize.org/prizes/chemistry/1965/woodward/biographical/"Robert Burns Woodward 
Week 9 Overview:  
https://boisestatecanvas.instructure.com/courses/28699/discussion_topics/679546

Class notes for Lectures 1-14: https://bricejurban.github.io/CHEM111/

Assignments this week:
﷟HYPERLINK "https://boisestatecanvas.instructure.com/courses/28699/assignments/1005559"Reading Quiz 6 (Chapter 10)
﷟HYPERLINK "https://boisestatecanvas.instructure.com/courses/28699/assignments/1005488"HW 8  - VSEPR and Valence Bond Theory
﷟HYPERLINK "https://boisestatecanvas.instructure.com/courses/28699/assignments/1005807"HW 9 - Nomeclature III, Chemical Reactions
Extra Credit Assignment:
﷟HYPERLINK "https://boisestatecanvas.instructure.com/courses/28699/assignments/1003293"Extra Credit: Molecular Orbital Theory (Chapter 9.1-9.4) 

Midterm 2: 
Grades are already entered on canvas and will be published on Gradescope after class. I will put the answer key outside SCNC 336. If you notice any errors in grading, please make a regrade request through Gradescope. 
Statistics (as %)*
Average: 72
Median: 74
St. Dev: 18
High: 105
*The exam is out of 94 points, because question 11 was thrown out.

Office Hours: 
Friday 11-1 CIC 
﷟HYPERLINK "https://calendly.com/bricejurban/office-hours"By appointment
 Reminder: 
Turn in ﷟HYPERLINK "https://boisestatecanvas.instructure.com/courses/28699/modules/items/3003193"Lecture 13 VSEPR Questions today or to Gradescope
﷟HYPERLINK "https://boisestatecanvas.instructure.com/courses/28699/assignments/993257"Emerging Tech in Chemistry  - is past due, please submit your presentation and comment on two others posts ASAP
Turn in ﷟HYPERLINK "https://boisestatecanvas.instructure.com/courses/28699/files/14539142?wrap=1"Lecture 14 VBT Questions today or to Gradescope


Chemistry Cat no Rxn.jpg Α SCIENCE ΙΟΚΕ 
(CHl)] 3 
42.ΒΙΙΤ ΙΤ ΡΑΟΒλΒΙΥ 
ΝΟ REACTION 
Chemistry isn't hard Learn the Rules.jpg Chemistry:isn't iPard 
Oust@llaw thistdne rüle)• 
the rylés 
i16arn all the ' 
to e rules 
Today's Schedule:
Tuesday (3/5)
Nomenclature III
Compounds with polyatomics
Acids
Hydrates
Chemical Reactions I
Combination (Synthesis) Rxns
Decomposition Rxns
Single and Double-Replacement
Combustion
Solubility
Dissolution Rxns
Looking Ahead
Thursday (3/7)
Chemical Reactions II
Substitution Rxns
Relative Activity of metals
Relative Activity of halogens
Neutralization Rxns
Oxidation-Reduction Rxns
Oxidation Numbers
(if time) Limiting Reactants and Percent Yield
Chemistry Cat no Rxn.jpg Α SCIENCE ΙΟΚΕ 
(CHl)] 3 
42.ΒΙΙΤ ΙΤ ΡΑΟΒλΒΙΥ 
ΝΟ REACTION 
Chemistry isn't hard Learn the Rules.jpg Chemistry:isn't iPard 
Oust@llaw thistdne rüle)• 
the rylés 
i16arn all the ' 
to e rules 

Characteristic patterns of the main reaction types
Synthesis, Decomposition, Single Replacement, Double Replacement, and Combustion
ChemicalReactionTypes.png Machine generated alternative text:
Types of Chemical Reactions 
1. Combination or Synthesis Reaction 
2. Decomposition Reaction 
3. Single-replacement Reaction 
4. Double-replacement Reaction 
5. Combustion Reaction 
0+0 

Example 1: Synthesis 

Mg(s)   +     O2(g)    ⟶     MgO(s)
Fphoto-30549111C-2RM.jpg ΛΠ-ΝΤΑ& 
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Mg(s)   +     O2(g)    ⟶     MgO(s)
`



Fphoto-30549111C-2RM.jpg ΛΠ-ΝΤΑ& 
Burning of magnesium ribbon
Example 2: Decomposition

water  ⟶  hydrogen + oxygen  





A5000247-Electrolysis_of_water.jpg EVEREADY 
Super Heavy puty 
Electrolysis of water
Example 3: Decomposition (dehydration of a hydrate)



                       Epsom salt (magnesium sulfate heptahydrate)    ⟶                   

                                   
Untitled picture.png 

Example 4: Single Replacement  (of a metal)

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Example 4: Single Replacement  (of a metal)




When zinc is placed in a solution of copper(II) sulfate it yields copper and aqueous zinc sulfate











Untitled picture.png Zn(s) 
CuS04(aq) 
Cu(sj: 
Displacement of copper by the more active metal zinc
Example 5: Single Replacement  (of a halogen)


                     Chlorine   +  Sodium bromide   ⟶




         
                     Chlorine   +  Sodium iodide ⟶




Untitled picture.png 
﷟HYPERLINK "https://www.youtube.com/watch?v=QHbaZFSU4_Q&t=795s""All in the Family" Properties of Halogens

Example 6: Double Replacement (Precipitation)
one product is an insoluble salt, or precipitate

potassium iodide (aq) + lead(II) chloride (aq) ⟶ lead(II) iodide + potassium chloride        
HYpkxLiFRnGevYjXUNIA_Fphoto-29919106A-2RM.jpg / 150 
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potassium iodide (aq) + lead(II) chloride (aq) ⟶ lead(II) iodide + potassium chloride        






HYpkxLiFRnGevYjXUNIA_Fphoto-29919106A-2RM.jpg / 150 
Titration of lead with potassium iodide
Example 7: Double Replacement (Neutralization)
ACID + BASE ⟶  SALT+ H2O

  perchloric acid (aq) + calcium hydroxide (aq) ⟶ Calcium perchlorate + water


 


C0430045-Acid-base_titration,_3_of_7.jpg 
Titration with phenolphthalein pH Indicator
Example 8: Double Replacement (Formation of a gas)
one product is a substance that forms a gas in aqueous solution. Here are some common gases that form:
H2S (g)
H2SO3 (aq) ⟶ SO2 (g) + H2O (l)
H2CO3 (aq)⟶ CO2 (g) + H2O (l)
NH4OH (aq)⟶ NH3 (g) + H2O (l)

        limestone + hydrochloric acid    ⟶ _______________________
  
201111-22.jpg 
Field test for limestone
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Field test for limestone
Example 9: Combustion          (First balance carbon, then hydrogen, last oxygen)

ethanol (l) + oxygen (g)  ⟶  carbon dioxide (g) + water (g)

lamp.jpg 
Ethanol being used as a lamp

Nomenclature III

Untitled picture.png Acids 
An acid is made of the H* ion and an anion (negative ion). 
In an aqueous solutm acids dissociate/ionize into ions. 
To name an acid: 
o If the anion ends in "—ide", then name the acid acid. " 
o If the anion ends in "mate", then name the acid acid. " 
If the anion ends in "mite", then name the acid acid." 


Hydrates
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Some salts can combine with water to form new compounds that incorporate water molecules into their molecular structure in specific whole-number ratios. Such water-containing compounds are called hydrates.
Example: copper(II) sulfate pentahydrate

Ionic compounds with Polyatomic ions
Polyatomic ions are ions composed of two or more atoms covalently bonded together, that function as a single charged entity.
Unlike monatomic ions, which consist of a single atom, polyatomic ions have a specific arrangement of atoms, often including oxygen, along with one or more other elements. 
These ions can have either a positive or negative charge, although negative polyatomic ions are more common.
The name of the polyatomic refers to the specific molecular formula and charge. Many sound similar learn the patterns
Hydrogen can also be present and they can be named as hydrogen or bi- ions.
The charge of the ions influences how they interact with ionic compounds
They also play crucial roles in biological processes.
This is a simplified list of the most common polyatomic ions.
Untitled picture.png acetate 
ammonium 
benzoate 
borate 
carbonate 
Table of Polyatomic Ions 
NH4+ 
C6H5C02- 
hydrogen carbonate HC03- 
perchlorate 
chlorate 
chlorite 
hypochlorite 
chromate 
CIO, 
C103 
C102- 
CIO 
crof- 
dichromate 
cyanide 
hydroxide 
iodate 
nitrate 
nitrite 
oxalate 
permanganate 
phosphate 
Cr207 
CN 
OH 
103- 
N03- 
N02- 
C2042 
MnO/ 
pot 
dihydrogen phosphate 
silicate 
sulphate 
sulphite 
hydrogen sulphide 
hydrogen sulphate 
hydrogen sulphite 
thiocyanate 
thiosulphate 
H2P04- 
Si03 
sof- 
S03 
HS04- 
HS03- 
SCN 
S2032- 
hydrogen phosphate HP042- 
CaCO₃
K₂SO₄
Cu(NO₃)₂
Zn(OH)₂
NH₄Cl
Ba(OH)₂
KNO₃
Li₃PO₄
Calcium sulfate
Aluminum nitrate
Sodium phosphate
Ammonium chloride
Copper(II) carbonate
Barium hydroxide
Sodium bicarbonate
Potassium permanganate

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Li₃PO₄
NiSO₄
Sr(NO₃)₂
Al(C₂H₃O₂)₃

Potassium permanganate
Lead(II) nitrate
Nickel(II) phosphate
Calcium hydroxide
Ammonium sulfate
Strontium chromate










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Solubility (Cover on Thursday)
Solute Solvent.png NaC1 
HO 
Solute 
Solvent 
NaCl (solute) + H2O (solvent)


Solute: What's being dissolved (usually the smaller part)
Solvent: What the solute is dissolved in (usually the larger part)

Untitled picture.png 들;이이 
이 후 2월) 
Dissolution equation:
NaCl (s) ⟶ Na+(aq) + Cl–(aq)

Dissolution: The process of dissolving a salt in water.
Solvation shells surround each ion which is what we indicate when we write aqueous (aq).
Note the negative end of the molecular dipole of water faces the positive charges and the positive end faces the negative charges.
Untitled picture.png 
Molecular equation:
NaCl(s) + H2O(l) ⟶ NaCl(aq)

Solution: A solute dissolved in a solution
Saturated solution: The maximum amount of solute that the given solvent can hold at a particular temperature
Unsaturated solution: A solution with less than the amount of solute needed for saturation
Supersaturated solution: A carefully prepared solution that contains more solute than a solvent can normaly hold. Prepared by carefully cooling a saturated solution
Embedded file printout Solubility rules Half_1.png Solubility: The ability of a substance, the solute, to form a solution with a solvent (e.g. water) 
General Solubility Rules for Ionic Compounds, applied in the order given: 
l. 
2. 
3. 
4. 
5. 
6. 
Most alkali metal salts and ammonium salts are soluble. 
Most nitrates, acetates, and perchlorates are soluble. 
Most silver, lead, and mercury(l) salts are insoluble. 
Most chlorides, bromides, and iodides are soluble. 
Most carbonates, chromates, sulfides, oxides, phosphates, and hydroxides are insoluble; except 
for hydroxides of Ba2+, Ca2+, and Sr2+ which are slightly soluble 
Most sulfates are soluble; except for calcium sulfate and barium sulfate which are insoluble. 
Solubility Rules for Salts 
Always soluble: 
• alkali ions, NH', N03-, C103-, C104-, C2H302-, HC03- 
Generally soluble: 
2 
Soluble except with Ag+, Pb2+, Hg22+ 
Soluble except with Pb2+ Ca2+ Ba2+ 
Soluble except with Pb2+, Ca2+, Ba2+ 
Sr2+, Mg2 
s 12+ 
Generally insoluble: 
02 , OH- 
Insoluble except with Ca2+ Ba2+ Sr2+ 
alkali ions, NH4 
coe- P043-, S2- S032-, Cr042-, C2042 
Insoluble except with alkali ions and NH4+ 
Strong Acids 
HCI, HBr, HI, HN03, H2S04, 
HC103, HC104, H104 
Gases that Form 
H2S (g) 
H2C03 (aq) C02 (g) + (C) 
H2S03 (aq) sch (g) + H20 (C) 
NH40H (aq) NH3 (g) + H20 (0 
Strong Bases 
Li0H, NaOH, KOH, RbOH, CsOH 
TIOH, 
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Embedded file printout Solubility rules Half_1.png Solubility: The ability of a substance, the solute, to form a solution with a solvent (e.g. water) 
General Solubility Rules for Ionic Compounds, applied in the order given: 
l. 
2. 
3. 
4. 
5. 
6. 
Most alkali metal salts and ammonium salts are soluble. 
Most nitrates, acetates, and perchlorates are soluble. 
Most silver, lead, and mercury(l) salts are insoluble. 
Most chlorides, bromides, and iodides are soluble. 
Most carbonates, chromates, sulfides, oxides, phosphates, and hydroxides are insoluble; except 
for hydroxides of Ba2+, Ca2+, and Sr2+ which are slightly soluble 
Most sulfates are soluble; except for calcium sulfate and barium sulfate which are insoluble. 
Solubility Rules for Salts 
Always soluble: 
• alkali ions, NH', N03-, C103-, C104-, C2H302-, HC03- 
Generally soluble: 
2 
Soluble except with Ag+, Pb2+, Hg22+ 
Soluble except with Pb2+ Ca2+ Ba2+ 
Soluble except with Pb2+, Ca2+, Ba2+ 
Sr2+, Mg2 
s 12+ 
Generally insoluble: 
02 , OH- 
Insoluble except with Ca2+ Ba2+ Sr2+ 
alkali ions, NH4 
coe- P043-, S2- S032-, Cr042-, C2042 
Insoluble except with alkali ions and NH4+ 
Strong Acids 
HCI, HBr, HI, HN03, H2S04, 
HC103, HC104, H104 
Gases that Form 
H2S (g) 
H2C03 (aq) C02 (g) + (C) 
H2S03 (aq) sch (g) + H20 (C) 
NH40H (aq) NH3 (g) + H20 (0 
Strong Bases 
Li0H, NaOH, KOH, RbOH, CsOH 
TIOH, 
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Insoluble salt
AgCl (s) ⇄ Ag+(aq) + Cl–(aq)
Untitled picture.png 
Polar covalent substance
CH3CH2OH(l)  ⟶CH3CH2OH(aq)

Polar solute & Polar solvent
Miscible (easy mixed)

Untitled picture.png 
Polar covalent substance
C12H22O11(s)  ⟶ C12H22O11(aq)

Polar solute & Polar solvent
Miscible
Untitled picture.png 
nonpolar covalent substance
C₁₆H₃₂O₂(s)  ⟶ NR

Nonpolar solute & Polar solvent
Immiscible (two layers)
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Strong Acid
HCl(aq)  ⟶ H+(aq) + Cl–(aq)
Strong acids are strong electrolytes
Untitled picture.png 
Weak Acid
HF(aq) ⇄ H+(aq)+ F–(aq)
Weak acids are weak electrolytes

 

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