Lecture 3 - Elements, Matter, and the Atom

Monday, January 15, 2024

11:58 AM

"Isotopes are atoms which have the same nuclear charge but different ﷟HYPERLINK "https://physics.nist.gov/cgi-bin/Compositions/stand_alone.pl"atomic weights."
﷟HYPERLINK "https://www.nobelprize.org/prizes/chemistry/1922/aston/biographical/"Francis William Aston (Biography)
﷟HYPERLINK "https://www.nobelprize.org/uploads/2018/06/aston-lecture.pdf"Francis W. Aston - Nobel Lecture 1922 - Great summary of what we will learn this week

﷟HYPERLINK "https://boisestatecanvas.instructure.com/courses/28699/discussion_topics/653829"This week's overview
Assignments this week:
﷟HYPERLINK "https://boisestatecanvas.instructure.com/courses/28699/assignments/983789"Reading quiz on sections 2.1-2.6 due on Wednesday.
﷟HYPERLINK "https://boisestatecanvas.instructure.com/courses/28699/assignments/984381"Reading quiz on sections 2.7-2.12 due on Friday.
﷟HYPERLINK "https://boisestatecanvas.instructure.com/courses/28699/assignments/984554"Homework 2 (chapter 2) on Aktiv Chemistry due on Sunday
Activity 1: ﷟HYPERLINK "https://boisestatecanvas.instructure.com/courses/28699/assignments/985392"Energy Source Investigation
Write-up by Wednesday (1/31) (2 weeks)
﷟HYPERLINK "https://boisestatecanvas.instructure.com/courses/28699/discussion_topics/654027"Peer reviews due Sunday (2/4) (18 days away)
Office Hours: 
Friday 11-1 CIC 
﷟HYPERLINK "https://calendly.com/bricejurban/office-hours"By appointment
Today's Schedule:
Composition of the Universe
Classifying matter
Pure substances (Elements and Compounds)
Mixtures (homogeneous and heterogeneous)
Classifying Energy
Explain Activity 1 
Classifying Forces
Elements Fun Facts
Law of Conservation of Mass, Constant Composition, and Multiple Proportions
Daltons Postulates of the Atom
Atomic Mass
Thursday's Schedule:
Structure of the Atom
Early experiments about the atom
Nomenclature I
Isotopic notation
Ions


Everything is composed of either matter or energy in ﷟HYPERLINK "https://youtu.be/u8lx19V7SNg?si=Q1W1DK9Z0ktZ4gQs"spacetime

Click this link to open a wall chart called the Correlated History of Matter
Includes: Timeline of Matter and Energy
Earth Rocks and Minerals
Meteorites and Rocks created by Impacts
 Periodic Table
Double click 
this icon
 Periodic Table
Fundamental Particles and Forces
this icon

Untitled picture.png Matter and energy 
in toda Is Universe 
Dark Energy 65% 
Dark Matter 30% 
Free Hydrogen 
4% 
and Helium 
Stars 
0.5% 
Heavy Elements 0.03% 

Dark matter is an invisible substance thought to make up about 27% of the universe's mass, influencing the motion of galaxies and galaxy clusters, while dark energy is a mysterious force driving the accelerated expansion of the universe, comprising about 68% of the universe's total energy content.

The remaining 5% of the universe is composed of ordinary, or "baryonic," matter, which includes everything that we can see, feel, and measure directly - stars, planets, galaxies, and all other forms of matter made up of atoms. This includes the energy associated with that matter.

How can we classify matter?
Matter makes up the substances in the universe
It is anything that has mass and takes up space 
We classify matter in terms of how it can be separated, either by physical or chemical means. 


   🍎
Embedded file printout Composition of Matter_1.png ixtu 
Is me composition unißrrn? 
atte 
Can it pnysica'y separated 
based on see, Censny. or 
physical property'? 
(Fitration. OistjllaW1. Evapuatjon, 
Decantabon. Magnebc Separation. 
Centrifugation, Chromatogram 
Sieving. Sedimentabon. Suünation, 
Extracton. Precimtabon, 
Recrystaüzabon. etc) 
ure Substan 
Can it be Chemicay 
aciCf--base 
omel chemical reactions) 
s disso 
14kt gold 
02 
58.5% Au 
440 ppm C02 
cu 
trace gases 
such as water 
14kt 'mite 
vapor and ozone 
58.5% 
115% Ni 
Am a" ams 
(Mercury ( F -"J 
another meta) 
A 
a nite 
Substance knownas 
a Solute dissolved 
in a liWid Solvent 
Meture 
(Components or phages 
'med Phase 
Emulsions 
that dont mix 
(Exam*- and water) 
SOWd that 
dissolve in a but 
remain even S 
(Examples. paint, bk)Od) 
Very rme particles 
dispersed another 
Can be solid 
•quid gas, etc 
Examples: Wk, Fog) 
or mue different elements 
Examples: 
Water ("20) 
Table san (Nacr) 
sucrose (C12H22011) 
Examples: 
Gold (Aul 
Alumnum (N) 
oxygen (02) 
Ozone (03) 
Nitogen (N2) 
(NaCl in Water) 
Sugar soX (Sucrose in 
Viegar (acetic n water)
Embedded file printout Composition of Matter_1.png ixtu 
Is me composition unißrrn? 
atte 
Can it pnysica'y separated 
based on see, Censny. or 
physical property'? 
(Fitration. OistjllaW1. Evapuatjon, 
Decantabon. Magnebc Separation. 
Centrifugation, Chromatogram 
Sieving. Sedimentabon. Suünation, 
Extracton. Precimtabon, 
Recrystaüzabon. etc) 
ure Substan 
Can it be Chemicay 
aciCf--base 
omel chemical reactions) 
s disso 
14kt gold 
02 
58.5% Au 
440 ppm C02 
cu 
trace gases 
such as water 
14kt 'mite 
vapor and ozone 
58.5% 
115% Ni 
Am a" ams 
(Mercury ( F -"J 
another meta) 
A 
a nite 
Substance knownas 
a Solute dissolved 
in a liWid Solvent 
Meture 
(Components or phages 
'med Phase 
Emulsions 
that dont mix 
(Exam*- and water) 
SOWd that 
dissolve in a but 
remain even S 
(Examples. paint, bk)Od) 
Very rme particles 
dispersed another 
Can be solid 
•quid gas, etc 
Examples: Wk, Fog) 
or mue different elements 
Examples: 
Water ("20) 
Table san (Nacr) 
sucrose (C12H22011) 
Examples: 
Gold (Aul 
Alumnum (N) 
oxygen (02) 
Ozone (03) 
Nitogen (N2) 
(NaCl in Water) 
Sugar soX (Sucrose in 
Viegar (acetic n water) 


How can we classify Energy?
Energy is what enables matter to move and change

Embedded file printout Energy Flowchart_1.png nerg 
n 
ne 
nti 
pcwet Plants stars 
crams Rubber Band 
(Uranium) (Hydrogen) 
Energy can transform from one form to another 
The Total energy in a closed system remains constant 





How can we classify Forces?
Forces are the interactions that dictate how energy and matter behave
Embedded file printout Forces Flowchart_1.png Force 
between charged partides Radioactive &cay 
Carried by mons Carried by W, Z particles 
FMce 01 attr action 
all masses 
Carried by gravitons? 
(not yet discovered) 
Structure ot universe 
Omits of *nets 
Terrestrial gravity 
In finite range 
A:ts on PMbcJeS 
Electriciy and Magnetism 
Electron-proton attracbon 
Electron• Electron repu On 
Much stronger 
than Gravity 
I nMite range 
Attractive Ot 
Acts on and leptons 
(e.g. nuclei and electons) 
weaker than EM 
but stronger than 
V" short range 
Acts on Warks. 
charged leptons, and 
Force that binds protons 
and neurons 
Carried b/ glums 
Holds nucleus togemer 
(the glue) 
Very st-Mt 
Acts on warts. 
and 'uons 
Higgs Fie 
A tied that 
gives mass to particles 
through the Higgs mechanism 
Carried by Hiws parbcÉ 
Not a force but essential 
lot the magg 01 W 
and Z particleswWch 
carry the weak force 
Peter Higgs 


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Embedded file printout Forces Flowchart_1.png Force 
between charged partides Radioactive &cay 
Carried by mons Carried by W, Z particles 
FMce 01 attr action 
all masses 
Carried by gravitons? 
(not yet discovered) 
Structure ot universe 
Omits of *nets 
Terrestrial gravity 
In finite range 
A:ts on PMbcJeS 
Electriciy and Magnetism 
Electron-proton attracbon 
Electron• Electron repu On 
Much stronger 
than Gravity 
I nMite range 
Attractive Ot 
Acts on and leptons 
(e.g. nuclei and electons) 
weaker than EM 
but stronger than 
V" short range 
Acts on Warks. 
charged leptons, and 
Force that binds protons 
and neurons 
Carried b/ glums 
Holds nucleus togemer 
(the glue) 
Very st-Mt 
Acts on warts. 
and 'uons 
Higgs Fie 
A tied that 
gives mass to particles 
through the Higgs mechanism 
Carried by Hiws parbcÉ 
Not a force but essential 
lot the magg 01 W 
and Z particleswWch 
carry the weak force 
Peter Higgs 






﷟HYPERLINK "https://www.youtube.com/watch?v=aZLvHM_mt6Y"Neil deGrasse Tyson explains the Higgs boson particle
BBC Radio 4

Neil deGrasse Tyson explains the Higgs boson particle Press enter to activate



﷟HYPERLINK "https://www.youtube.com/watch?v=cK2SVfDMMrU"The Periodic Table Song with real elements
The Periodic Table Song with real elements Press enter to activate
The Periodic Table Song with real elements Press enter to activate

Elements
Multivitamin.JPG Amount Per Sewing 
Caldtrn 
% value 
210 mg 
(a Camm Catbmate & Dcaäum Phosphate) 
1m (a Fns Furrate) 
8 mg 
20 mg 
une (c Potassium Iodide) 
150 mcg 
Magnæn(cMqrBitmOide) 100 mg 
Zrc(aZncOxjde) 
11 mg 
Eium(aSodunSdenate) 100 mcg 
(a Sulfate) 
0.9 mg 
Manganese SUfate) 2.3 mg 
Chromium (as Chromium Picolirnte) 35 mcg 
Molybdenum (as Sodium Mob,'bdate) 50 mcg 
Chloride@Potasin Chloride) 72 mg 
Potasium (as Potasium Chloride) 80 mg 
2% 
100% 
100% 
182% 
100% 
100% 
100% 
111% 
3% 
The elements are necessary for life as we know it.
There are 94 naturally occurring elements on Earth. (Hydrogen through 
Plutonium)
80 of these from Hydrogen (element 1) to Lead (element 82) have at least one stable isotope that does not undergo radioactive decay. (Technetium (element 43) and Promethium (element 61) are notable exceptions)
80 of these from Hydrogen (element 1) to Lead (element 82) have at least one stable isotope that does not undergo radioactive decay. (Technetium (element 43) and Promethium (element 61) are notable exceptions)
The transuranium elements are synthetic and have been artificially produced through nuclear reactions. (elements with greater than 92 protons).
As of now, scientists have discovered 118 elements, the last of which is element 
Oganesson (Og) and named after living scientist Yuri Oganessian, a Russian nuclear physicist who significantly contributed to the discovery of superheavy elements. 
The most recent element to be discovered was element 117 Tennessine in April 2010 (during your lifetime!) by a collaboration of Russian scientists at the Joint Institute for Nuclear Research in Dubna, Russia, and American scientists at the Oak Ridge National Laboratory in Tennessee, USA.
Some elements have been known since antiquity, but the discovery of most was not an easy feat. Most elements are present in very trace amounts, and almost none are present in pure form and therefore must be isolated.
The hunt for new elements has not abated. I predict that element 119 or 120 will be discovered in our lifetime and then we will have to add another row to our periodic table. That will be truly an amazing day.
Is there a fundamental limit? Some physicists believe that there is an ﷟HYPERLINK "https://en.wikipedia.org/wiki/Island_of_stability"island of stability in the region of superheavy elements that would have longer half-lives. Additionally some quantum theorists believe that in the theoretical element 137, the electromagnetic radiation would compete with the nuclear force so strongly that speeds faster than the speed of light would be necessary (impossible), so the atom would be inherently unstable. 
Applying atomic theory we can understand the differences in the elements through their subatomic particles. 
The chemical properties of an element depend solely on its atomic number (Z), which is the charge on its nucleus expressed in terms of the unit charge, e.
Therefore the elements are arranged 1 through 118 on the periodic table simply by the numbers of protons that they contain in their nucleus. 
Atomic symbols









An appeal to memorize these ﷟HYPERLINK "https://quizlet.com/814496647/elemental-symbols-and-names-flash-cards/?funnelUUID=983fdaf0-ec1f-4aeb-b943-1404b11cef95"50 elements
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The second letter must be lowercase
The isotopes of hydrogen
get their own letter
An appeal to memorize these ﷟HYPERLINK "https://quizlet.com/814496647/elemental-symbols-and-names-flash-cards/?funnelUUID=983fdaf0-ec1f-4aeb-b943-1404b11cef95"50 elements

The three Laws that led to the Atom
Law of Conservation of Mass
In a chemical reaction, the total mass of the reactants is equal to the total mass of the products formed.
Parents of Modern Chemistry
Lavoisier_and_His_Wife.jpg 
Antoine Lavoisier and 
Marie Anne Lavoisier
Law of Constant Composition
(Definite Proportions)
The relative amount of each element in a particular compound is always the same. Regardless of origin or preparation









Untitled picture Image result for proust chemist

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get their own letter




Law of Multiple Proportions
When a given element combines with another element to form two different compounds, for a fixed mass of the first, the ratio of the two compounds consists of small whole numbers
A014739_John-Dalton-founder-of-chemical-atomic-theory.jpg John Dalton, founder of chemical atomic theory stock image | Look and Learn
John Dalton


Daltons Postulates
All matter is made of atoms that are indivisible
All atoms of a given element are identical in mass and properties
Atoms of different elements differ in mass and properties
Compounds are formed by a combination of two or more different kinds of atoms
A chemical reaction is a rearrangement of atoms, no atoms are created, destroyed, or transmuted.

Atomic Masses are Relative

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1/12 of 12 grams of carbon-12
Dalton misinterpreted the data.
He assumed elements were only monoatomic
This is not true!
DaltonsElements.jpg 0 
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Practice
Explain how you could separate table salt, NaCl(s), from sand.

Add deionized (DI) water to the mixture to dissolve the salt. Decant or filter out the sand, then dry. Evaporate the water from the salt water mixture to recover the salt.

A 1.28-gram sample of copper is heated with sulfur to produce 1.60 grams of a copper sulfide compound. Calculate the mass percentages of copper and sulfur in the compound.





Sulfur forms two oxides. In one of them, 1.87 grams of sulfur combines with 1.87 grams of oxygen, and in the other 3.94 grams of sulfur combines with 5.91 grams of oxygen. Show how these data illustrate the law of multiple proportions.


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sulfur + oxygen
sulfur/g
oxygen/g
ratio sulfur:oxygen
Compound 1
1.87
1.87
1.00:1.00 
Compound 2
3.94
5.91
0.666:1.00 or 2.00:3.00

The simplest ratio of sulfur to oxygen in the first compound is 1:1 
In the second compound if should recognize that 0.666 is ﷐𝟐﷮𝟑﷯. 
by multiplying the ratio by 3 it is easier to see the whole number ratio is 2:3

The first compound might have the chemical formula SO, or S2O2, or S3O3, etc.
In the second compound the data suggest the formula S2O3 or higher multiples.

The data indicates the ratio of the two compounds is in whole number ratios and this illustrates the law of multiple proportions.

(The use of moles or atomic masses is not needed here).


Suppose we decide to establish an atomic mass scale by setting the atomic mass of 12C exactly equal to one. What would be the atomic masses of naturally occurring hydrogen and oxygen on this scale?

The atomic mass of 12C is normally 12.000 but in this system it is 1.000. We need to just use simple ratios to determine the new atomic masses of hydrogen and oxygen
﷐12.000﷮1.008﷯=﷐1.000﷮﷐H﷮∗﷯ amu﷯
﷐12.000﷮16.00﷯=﷐1.000﷮﷐O﷮∗﷯ amu﷯
H* = 0.0840 amu
O* = 1.333 amu
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